| Information | |
|---|---|
| has gloss | eng: The Carroll rearrangement is a rearrangement reaction in organic chemistry and involves the transformation of a β-keto allyl ester into a α-allyl-β-ketocarboxylic acid. This organic reaction is accompanied by decarboxylation and the final product is a γ,δ-allylketone. The Carroll rearrangement is an adaptation of the Claisen rearrangement and effectively a decarboxylative Allylation. |
| lexicalization | eng: Carroll rearrangement |
| instance of | (noun) a silver-white metallic element of the platinum group that resembles platinum; occurs in some copper and nickel ores; does not tarnish at ordinary temperatures and is used (alloyed with gold) in jewelry palladium, Pd, atomic number 46 |
| Meaning | |
|---|---|
| Japanese | |
| has gloss | jpn: キャロル転位（キャロルてんい、Carroll rearrangement）とは、有機化学における人名反応のひとつで、β-ケト酸のアリルエステルが [3,3]-シグマトロピー転位（クライゼン転位に相当）を起こした後に脱炭酸を起こし、生成物として γ,δ-不飽和ケトンを与える反応 。 |
| lexicalization | jpn: キャロル転位 |
| Chinese | |
| has gloss | zho: Carroll重排反应（卡罗尔重排），又称Carroll–Claisen重排反应 |
| lexicalization | zho: Carroll重排反应 |
| Media | |
|---|---|
| media:img | AsymmetricCarrol2005.png |
| media:img | AsymmetricCarrolRearrangement.gif |
| media:img | Carrol rearrangement reaction mechanism.gif |
| media:img | Decarboxylative allylation mechanistic.png |
| media:img | DecarboxylativeAllylation.png |
| media:img | DecarboxylativeAllylationTrost2005.png |
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