e/Coordination polymerization

Information
has gloss	eng: Coordination polymerization is a form of addition polymerization in which monomer adds to a growing macromolecule through an organometallic active center. The development of this polymerization technique started in the 1950s with heterogeneous Ziegler-Natta catalysts based on titanium tetrachloride and an aluminium co-catalyst such as methylaluminoxane. Coordination polymerization has a great impact on the physical properties of vinyl polymers such as polyethylene and polypropylene compared to the same polymers prepared by other techniques such as free radical polymerization. The polymers tend to be linear and not branched and have much higher molar mass. Coordination type polymers are also stereoregular and can be isotactic or syndiotactic instead of just atactic. This tacticity introduces crystallinity in otherwise amorphous polymers. From these differences in polymerization type the distinction originates between low density polyethylene (LDPE), high density polyethylene (HDPE) or even ultra high molecular weight polyethylene (UHMWPE). Polymerizations catalysed by metallocenes occur via the Cossee-Arlman mechanism.
lexicalization	eng: Coordination polymerization
instance of	(noun) a chemical process that combines several monomers to form a polymer or polymeric compound polymerization, polymerisation